J. Phys. Chem. B,103 (17), 3361 -3365, 1999.
Copyright © 1999 American Chemical Society
Sonochemical Preparation and Characterization of Eu2O3
and Tb2O3 Doped in and Coated on Silica and Alumina
Nanoparticles
A. Patra, E. Sominska, S. Ramesh, Yu. Koltypin, Z. Zhong, H. Minti, R. Reisfeld, and A. Gedanken
Department of Inorganic and Analytical Chemistry, The Hebrew University
of Jerusalem, 91940 Israel, and Department of Chemistry, Bar-Ilan University,
Ramat-Gan 52900, Israel
Received: December 17, 1998
In Final Form: February 24, 1999
Abstract:
Submicron size spheres of silica and alumina prepared by well-known
methods were coated sonochemically by nanoparticles of oxides of europium
and terbium using the same concentration of ions. We have also used sonochemistry
to prepare nanoparticles of silica and alumina doped by the same rare-earth
ions for comparison. The highest luminescence intensities were observed
for europium and terbium doped in nanoparticles of alumina of dimension
20-30 nm. The intensities are comparative or higher than in commercial
phosphors.